本帖最后由 永颉同心 于 2011-10-27 08:56 编辑
贵州毕节地区煤层中稀土元素在含煤地层划分与对比中应用探讨
王强 杨瑞东 鲍淼
摘 要:稀土元素是良好的地质指示剂,以晚二叠世黔西毕节地区可采煤层中的REE(稀土元素)为研究对象,探讨REE在煤系地层对比、划分中的应用问题.结果显示REE(轻稀土元素)的含量在龙潭组与长兴组的界线附近存在着异常富集的现象,∑REE的含量在界线附近也存在着异常富集的现象.REE在界限附近的异常富集是其物源(间歇性和多旋回性喷发的峨眉山玄武岩)和成煤期频繁的海进海退共同作用的结果.因此,在具有相同物源的地区,可以利用稀土含量的变化,进行煤层和地层的对比、划分,并有可能研究海平面的变化.
关键词:稀土元素;地层;物源;海进海退;毕节
基金项目:贵州省科技厅基金(200503),博士点建设基金资助.
作者简介:王强 男 1977年出生 在读博士 地球化学 E-mail:wqwqqiang@126.com
作者单位:王强(中国科学院广州地球化学研究所同位素年代学与地球化学重点实验室,广州,510640;中国科学院研究生院,北京,100049)
杨瑞东(贵州大学资源与环境工程学院,贵阳,550003)
鲍淼(贵州大学资源与环境工程学院,贵阳,550003)
参考文献:
[1]赵志根,唐修义,杨起,等.哈密、淮北煤变质程度与稀土元素的关系研究[J].中国矿业大学学报,2001,30(2):165-169[Zhao Zhigen,Tang Xiuyi,Yang Qi,et al.Research on relationship between ranks of coal and geochemical features of REE in Hami and Huaibei coal[J].Journal of China University of Mining & Technology,2001,30(2):165-169]
[2]Li Dahua,Tang Yuegang,Chen kun,et al.Concentration,distribution,and occurrence of REEs in coal from Chongqing,Southwest China[J].China Univ.of Mining & Tech,2005,15(3):227-233
[3]郑刘根,刘桂建,张浩原,等.淮北煤田二叠纪煤中稀土元素地球化学研究[J].高校地质学报,2006,12(1):41-52[Zheng Liugen,Liu Guijian,Zhang Haoyuan,et al.Study on geochemistry of rare earth elements(REEs)in Permian coal from Huaibei coalfield[J].Geological Journal of China Universities,2006,12(1):41-52]
[4]Bouska V.Geochemistry of Coal[M].Amsterdam:Elsevier,1981:284-294
[5]Yudovich Ya E,Ketris M P,Mertz A V.Elements-admixtures in Coals (in Russian)[M].Leningrad:Nauka Press,1985:239-243
[6]Brik D,White J C.Rare elements in bituminous coals and underclays of the Sydney Basin,Nova Scotia:Element sites,distribution,mineralogy[J].International Journal of Coal Geology,1991,19:219-251
[7]Ren Deyi,Zhao Fenghua,Wang Yunquan.Distribution of minor and trace elements in Chinese coals[J].International Journal of Coal Geology,1999,4:109-118
[8]Dai Shifeng,Ren Deyi,Hou Xiaoqiang,et al.Geochemical and mineralogical anomalies of the Late Permian coal in the Zhijin coalfield of southwest China and their volcanic origin[J].International Journal of Coal Geology,2003,55:117-138
[9]Dai Shifeng,Ren Deyi,Tang Yuegang,et al.Concentration and distribution of elements in Late Permian coals from western Guizhou Province,China[J].International Journal of Coal Geology,2004,61:119-137
[10]Dai Shifeng,Chou C L,Yue Mei,et al.Mineralogy and geochemistry of a Late Permian coal in the Dafang Coalfield,Guizhou,China:influence from siliceous and iron-rich calcic hydrothermal fluids[J].International Journal of Coal Geology,2005,61:241-258
[11]刘季辰,赵汝均.江苏地质志[C].南京前)中央地质调查所,地质专报,甲种4号,1924:1-33[Liu Jichen,Zhao Rujun.Jiangsu Geological History.(before) Central Geological Survey,the Geological Report,1924:5-24]
[12]李四光,朱森.南京龙潭地质指南[M].南京前)国立中央研究院地质研究所,1932:1-13[Li Siguang,Zhu Sen.Geological Guide of Longtan in Nanjing[M].NanjingFormer) Institute of Geology,National Academy of Sciences,1932:1-13]
[13]盛金章.中国的二叠系全国地层会议学术报告汇编[C].北京:科学出版社,1962:1-95[Sheng Jinzhang.National academic conference collection of Chinese Permian strata[C].Beijing:Science Press,1962:1-95]
[14]姚兆奇,李成栋.龙潭组的定义和时代[J].地层学杂志,1984,8(3):199-214[Yao Zhaoqi,Li Chengdong.The definition and age of Longtan Formation[J].Journal of Stratigraphy,1984,8(3):199-214]
[15]Grabau A W.Devonian brachiopoda of China[J].Palaeontologia Sinica,Series B,1931,3:526-538
[16]金玉玕,王向东,尚庆华,等.中国二叠纪年代地层划分和对比[J].地质学报,1999,73(2):97-108[Jin Yugan,Wang Xiangdong,Shang Qinghua,et al.Chronostratigraphic subdivision and correlation of the Permian in China[J].Acta Geologica Sinica,1999,73(2):97-108]
[17]李振祥主编.煤炭常用标准汇编[M].北京:煤炭工业出版社,2000:204-207[Li Zhenxiang ed.Coal common standard collection[M].Beijing:Coal Industry Press,2000.204-207]
[18]黄思静,石和,张萌,等.上扬子石炭-二叠纪海相碳酸盐的锶同位素演化与全球海平面变化[J].沉积学报,2001,19(4):481-487[Huang Sijing,Shi He,Zhang Meng,et al.Strontium isotope evolution and global sea-level changes of carboniferous and Permian marine carbonate,Upper Yangtze platform[J].Acta Sedimentologica Sinica,2001,19(4):481-487]
[19]谢渊,王剑,刘家铎,等.羌塘盆地那底岗日地区中侏罗世层序地层与碳、氧、锶同位素响应[J].沉积学报,2002,20(2):188-196[Xie Yuan,Wang Jian,Liu Jiaduo,et al.Carbon,oxygen and strontium isotopic responses of carbonate rocks and the Middle Jurassic sequence stratigraphy in the Nadigangri Area,Qiangtang Basin[J].Acta Sedimentologica Sinica,2002,20(2):188-196]
[20]黄思静,石和,张萌,等.锶同位素地层学在奥陶系海相地层定年中的应用--以塔里木盆地塔中12井为例[J].沉积学报,2004,22(1):1-5[Huang Sijing,Shi He,Zhang Meng,et al.Application of strontium isotope stratigraphy to dating Ordovician marine sediments:a case study from the Well Tazhong 12 in Tarim Basin[J].Acta Sedimentologica Sinica,2004,22(1):1-5]
[21]王强,杨瑞东,鲍淼,等.毕节煤矿区晚二叠世煤层稀土元素的物质来源[J].贵州地质,2006,26(4):130-134[Wang Qiang,Yang Ruidong,Bao Miao,et al.Substance sources of rare -earth elements in Late Permian coal seams on coal mines in Bijie[J].Guizhou Geology,2006,26(4):130-134]
[22]Zhuang Xinguo,Querol X,Plana F,et al.Determination of elemental affinities by density fractionation of bulk coal samples from the Chongqing coal district,Southwestern China[J].International Journal of Coal Geology,2003,55:103-115
[23]杜美霞,庄新国.华南地区晚二叠和晚三叠世煤中稀土元素特征研究[J].中国煤田地质,2006,18(2):22-27[Du Meixia,Zhuang Xinguo.A characteristic study of rare-earth elements in Southern China Late Permian and Late Triassic coals[J].Coal Geology of China,2006,18(2),22-27]
[24]陈文一,刘家仁,王中刚,等.贵州峨眉山玄武岩喷发期的岩相古地理研究[J].古地理学报,2003,5(1):17-28[Chen Wenyi,Liu Jiaren,Wang Zhonggang,et al.Study on lithofacies palaeogeography during the Permian Emeishan basalt explosion in Guizhou Province[J].Journal of Palaeogeography,2003,5(1):17-28]
[25]冯增昭,金振奎,杨玉卿,等.滇黔桂地区二叠纪岩相古地理[M].北京:地质出版社,1994:73-86[Feng Zengzhao,Jin Zhenkui,Yang Yuqing,et al.Lithofacies Paleogeography of Permian of Yunnan-Guizhou-Guanxi Region[M].Beijing:Geological Publishing House,1994:73-86]
[26]杨玉卿,冯增昭.中国南方二叠纪沉积体系[J].古地理学报,2000,2(1):11-18[Yang Yuqing,Feng Zengzhao.Permian depositional system in south China[J].Journal of Palaeogeography,2000,2(1):11-18]
[27]向英福,陈宗富.贵州晚二叠世沉积相及其演变规律探讨[J].贵州地质,1989,6(3):191-202[Xiang Yingfu,Chen Zongfu.A discussion on sedimentary facies of Late Permian and its evolutionary law in Guizhou[J].Geology of Guizhou,1989,6(3):191-202]
[28]毛德明,张启厚,安树仁.贵州西部峨眉山玄武岩及其矿[M].贵阳:贵州科技出版社,1992:24-32[Mao Deming,Zhang Qihou,An Shurei.Emeishan basalt and minerals of western Guizhou[M].Guiyang:Guizhou Science and Technology Press,1992:24-32]
[29]王立亭,罗晋辉,王常微,等.贵州西部晚二叠世近海煤田地质特征及聚煤规律[J].贵州地质,1993,37(4):291-300[Wang Liting,Luo Jinhui,Wang Changwei,et al.Geology and coal-accumulating regularity of the paralic coal fields of Late Permian in western Guizhou[J].Geology of Guizhou,1993,37(4):291-300]
[1]向英福,马忠魏,梁福京,等.贵州晚二叠世煤田地质报告.1987
[2]杨瑞东.贵州晚二叠世岩相古地理与聚煤环境研究[硕士学位论文].贵阳:贵州工学院,1989.
|