[align=justify]摘 要:土壤和沉积物中重金属被植物吸收利用可通过单一化学萃取方法评估.几种重金属生物可利用态的萃取方法被用于土壤和沉积物中重金属的提取.根据实验萃取结果和文献报道,对中性盐、弱酸、螯合荆和联合萃取法进行评价,对影响生物可利用态萃取方法的因素进行讨论,并对土壤和沉积物中重金属生物可利用性评价方法的建立和有效统一使用提出建议.
关键词:土壤;沉积物;重金属;生物可利用性;单一萃取
分类号:O655.6;O652.62 文献标识码:A
文章编号:0254-5357(2009)02-0108-05Evaluation of Bioavailability of Heavy Metals in Soils and Sediments WANG Chang GUO Peng-ran CHEN Hang-ting SHU Yong-hong
基金项目:国家自然科学基金项目资助(20677057)
作者简介:王畅(1979-),女,湖北黄冈人,硕士,研究方向为重金属环境化学形态分析.E-mail:chwang.1979@gmail.com.
作者单位:王畅(中国广州分析测试中心,广东,广州,510070)
郭鹏然(中国广州分析测试中心,广东,广州,510070;中山大学环境科学与工程学院,广东,广州,510275)
陈杭亭(中国科学院长春应用化学研究所国家电化学和光谱研究分析中心,吉林,长春,130022)
舒永红(中国广州分析测试中心,广东,广州,510070)
参考文献:
[align=justify][1]李书鼎.污染生态物理化学[M].北京:中国环境科学出版社,2002:3-7,98-107.
[2]刘文长,马玲,刘洪青,潘同应,徐厚玲.生态地球化学土壤样品元素形态分析方法研究[J].岩矿测试,2005,24(5):181-188.
[3]王亚平,黄毅,王苏明,许春雪,刘妹.土壤和沉积物中元素的化学形态及其顺序提取法[J].地质通报,2005,24(8):728-734.
[4]钱进,王子健,单孝全.土壤中微鼍金属元素的植物可给性研究进展[J].环境科学,1995,16(6):73-78.
[5]Alexander M.Aging,bioavailability and overestimation of risk from environmental pollutants[J].Environmental Science and Technology,2000,34:4259-4265.
[6]Peijnenburg W,Baersolman R,Groot A,Jager T,Leenders D,Pesthuma L,Van Veen R.Quantification of metal bioavailability for lettuce in field soils[J].Archives of Environmental Contamination and Toxicology,2000,39:420-430.
[7]Ure A,Quevauviller Ph,Muntau H,Griepink B.Speciation of heavy metals in soils and sediments.An account of the improvement and harmonization of extraction techniques undertaken under the auspices of the BCR of the commission of the European communities[J].Intenrational Journal of Environmental Amalyical Chemistry,1993,51:135-151.
[8]Quevanviller Ph.Operationally defined exhnetion procedures for soft and sediment analysis.i.Standardization[J].Trends in Analytical Chemistry,1998,17(5):289-297.
[9]刘玉荣,党志,尚爱安,文震.几种萃取剂对土壤中重金属生物有效部分的萃取效果[J].土壤与环境,2002,11(3):245-247.
[10]尚爱安,党志,梁重山.土壤/沉积物中微量重金属的化学萃取方法研究进展[J].农业环境保护,2001,20(4):266-269.
[11]Rauret G.Extraction procedure for the determination of heavy metals in contaminated soil and sediment[J].Talanta,1998,46:449-455.
[12]Feng M H,Shan X Q,Zhang S Z,Wen B.A comparison of the rhizosphere-based method with DTPA,EDTA,CaCl2 and NaNO3 extraction methods for prediction of bioavailability of metals in soil to barley[J].Environmental Pollution,2005,137:231-240.
[13]Fangueiro D,Bermond A,Santos E,Carapuea H.Duarte A.Heavy metal mobility assessment based on a kinetic appraeh of the EDTA extraction:Search for optimal experimental conditions[J].Analytica Chimica Acta,2002,459:245-256.
[14]Pueyo M,Lopez-Sanchez,Rauret G.Assessment of CaCl2,NaNO3 and NH4NO3 extraction procedured far the study of Cd,Cu,Pb and Zn extraetability in contaminated soils[J].Andytica Climica Acta,2004,504:217-226.
[15]王学锋,杨艳琴.土壤-植物系统重金属形态分析和生物有效性研究进展[J].化工环保,2004,24(1):24-27.
[16]Quevauviller Ph,Rauret G,Rubio R,López-Sánchez J F,Ure A,Bacon J,Muntan H.Certified reference materials for the quality control of EDTA-and acetic acid-extractable contents of trace elements in sewage sludge amended soils(CRMs 483 and 484)[J].Fresenius' Journal of Analytical Chemistry,1997,357:611-618.
[17]郭鹏然,段太成,刘欣丽,陈杭亭.粘粒和阳离子交换量对包头土壤中钍的形态分布的影响[J].环境化学,2009,28(1):76-79.
[18]Sterckeman T,Gomez A,Ciesielski H.Soil and waste analysis for environmental risk assessment in France[J].Science of the Total Enviroment,1996,178(1-3):62-69.
[19]李非里,刘丛强,宋照亮.土壤中重金属形态的化学分析综述[J].中国环境监测,2005,21(4):21-27.
[20]Guo P R,Duan T C,Song X J,Xu J W,Chen H T.Effects of soil pH and soil organic matter on distribution of thorium fractions in soil contaminated by rare earth industries[J/OL].Talanta,2008,doi:10.1016/j.talanta.2008.06.002.
[21]Takeda A,Tsukada H,Takaku Y,Hisamatsu S,Inaba J,Nanzyo M.Extractability of major and trace elements from agricultural soils using chemical extraction methods:Application for phytoavailability assessment[J].Soil Science and Plant Nutrition,2005,52(4):406-417.
[22]Sauerbeck D R,Styperek P.Evaluation of chemical methods for assessing the cadmium and zinc availability from different soils and sources.Comm.Eur.Communities,EUR,(EUR 9538,Chemical Methods Assess.Bio-Available Met.Sludges Soils),1985:49-66.
[23]Yin Y,Impellitteri C A,You S J,Allen H E.The importance of organic matter distribution and extract soil:solution ratio on the desorption of heavy metals from soils[J].Science of the Total Environment,2002,287:107-119.
[24]Usero J,Gamero M,Morillo J,Gracia I.Comparative study of three sequential extraction procedures for metals in marine sediments[J].Environment International,1998,24(4):487-496.
[25]Kennedy V H,Sanchez A L,Oughton D H,Rowland A P.Use of single and sequential chemical extractants to agsess radionuclide and heavy metal availability from soils for root uptake[J].The Analyst,1997,122:89R-100R.
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