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电子探针背景扣除和谱线干扰修正方法的进展

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发表于 2010-7-17 00:05 | 显示全部楼层 |阅读模式
电子探针背景扣除和谱线干扰修正方法的进展

姚立  田地  梁细荣 

摘 要:对提高电子探针分析精度和分辨本领的关键和难点--背景扣除和重叠峰修正的理论和方法发展进行了综述.介绍了避免谱线干扰的方法和计算谱线干扰量的主要算法及软件应用效果,包括估计干扰因子法、模拟元素谱图法、最小二乘方拟合法及谱线去卷积运算法.讨论了分析中的背景来源及非线性背景扣除的理论和方法发展,并对背景和谱线干扰修正的发展前景进行了展望.引用文献62篇.
关键词:电子探针分析;背景扣除;谱线干扰修正;综述
分类号:P575.1  文献标识码:A
文章编号:0254-5357(2008)01-0049-06

Progress in Background Subtraction and Spectral Interference Correction in Electron Probe Microanalysis

YAO Li  TIAN Di  LIANG Xi-rong 



基金项目:国家科技基础平台建设重点项目资助(2005DKA10103)
作者简介:姚立(1968-),女,吉林长春市人,博士生,从事大型分析仪器的技术改造及分析测试方法研究.
作者简介:田地(1958-),男,吉林前郭县人,博士,教授,从事分析仪器技术开发及其测控系统研究. E-mail:tiandi@jlu.edu.cn.通讯作者
作者单位:姚立(吉林大学测试科学实验中心,吉林,长春,130026;吉林大学仪器科学与电气工程学院,吉林,长春,130061) 
     田地(吉林大学仪器科学与电气工程学院,吉林,长春,130061) 
     梁细荣(中国科学院广州地球化学研究所同位素年代学和地球化学重点实验室,广东,广州,510640) 

参考文献:

[1]Petrik I,Konecny P,Kovacik M,et al.Electron Microprobe Dating of Monazite from the Nizke Tatry Mountains Orthogneisses (Western Carpathians,Slovakia)[J].Gelologica Carpathica,2006,57 (4):227-242.
[2]Lisowiec N.Precision Estimation in Electron Microprobe Monazite Dating:Repeated Measurements Versus Statistical (Poisson) Based Calculations[J].Chemical Geology,2006,234 (3-4):223-235.
[3]Cocherie A,Legendre O.Potential Minerals for Determining U-Th-Pb Chemical Age Using Electron Microprobe[J].Lithos,2007,93 (3-4):288-309.
[4]Mónaco S L,López L,Rojas H,et al.Applications of Electron Microprobe Analysis (EPMA) in the Study of Venezuelan Source Rocksa Luna and Querecual Formations[J].Fuel,2007,86 (5-6):641-648.
[5]郭国林,潘家永,刘成东,等.电子探针化学测年技术及其在地学中的应用[J].华东理工学院学报,2005,28(1):39-42.
[6]周剑雄,陈振宇,芮宗瑶.独居石的电子探针钍-铀-铅化学测年[J].岩矿测试,2002,21(4):241-246.
[7]Love G.EPMA Present and Future[J].Mikrochimica Acta,2002,138 (3 -4):223-235.
[8]Rémond G,Myklebust R,Fialin M,et al.Decomposition of Wavelength Dispersive X-ray Spectra[J].Journal of Research of the National Institute of Standards and Technology,2002,107 (6):509-529.
[9]Kim,HyekyeongHwan,Hee Jin,et al.Single-particle Characterization of Soil Samples Collected at Various Arid Areas of China,Using Low-Z Particle Electron Probe X-ray Microanalysis[J].Spectrochimica Acta-Part B Atomic Spectroscopy,2006,61 (4):393 -399.
[10]姚立,田地.电子探针定性分析软件的研究与开发[J].电子显微学报,2003,22(1):71-74.
[11]徐乐英,尚玉华,郭延风,等.用电子探针定量分析超轻元素中的几个问题[J].分析测试学报,1994,13(5):37-41.
[12]Geller D J,Herrinqton C.High Count Rate Electron Probe Microanalysis[J].Journal of Research of the National Institute of Standards and Technology,2002,107(6):503 -508.
[13]Fialin M,Remy H,RIchard C,et al.Trace Element Analysis with the Electron Microprobe:New Data and Perspectives[J].American Mineralogist,1999,84:70-77.
[14]Anwar U H,Tawancy H M,Mohammed A R I,et al.Quantitative WDS Analysis Using Electron Probe Microanalyzer[J].Materials Characterzation,2006,56:192-199.
[15]彭松柏,朱家平,李志昌,等.国外电子探针铀-钍-铅定年方法及其在构造分析中的应用前景[J].岩矿测试,2004,23(1):44-51.
[16]张文兰,王汝成,华仁民,等.副矿物的电子探针化学定年方法原理及应用[J].地质论评,2003,49(3):253-260.
[17]姚立,田地,王微.电子探针特征X射线谱线识别的方法研究[J].电子显微学报,2004,23(4):425-426.
[18]Reed S J B.Optimization of Wavelength Dispersive X-ray Spectrometry Analysis Conditions[J].Journal of Research of the National Institute of Standards and Technology,2002,107:497-502.
[19]Shimadzu Corp.EPMA-1610 Electron Probe Micro -analyzers[EB/OL].http:// www.shimadzu.com/products/lab/surface/epma.html 2007/05/13.
[20]Cameca.SX100 Universal EPMA[EB/OL].http://www.cameca.fr/html/product_sx100.html 2007/05/12.
[21]JEOL LTD.JXA-8200 X-ray Mircoanalyzers[EB/OL].http:// www.jeol.com/sa _/saprods/jxa8200.html 2007/05/13.
[22]Ohmori T.Electron Probe Microanalysis,EPMA[J].J Japanese Society of Tribologists,Recent Topics on Contact Problems,2005,5 (7):523-527.
[23]毛允静.钢中低碳的电子探针定量分析[J].冶金分析,2003,23(1):59-62.
[24](A)mli R,Griffen W.Microprobe Analysis of REE Minerals Using Empirical Correction Factors[J].American Mineralogist,1975,60:599-606.
[25]Roeder P L.Electron-microprobe Analysis of Minerals for Rare-earth Elements:Use of Calculated Peakoverlap Corrections[J].Canadian Mineralogist,1985,23:263-271.
[26]周剑雄,毛水和,陈克樵,等.电子探针分析[M].北京:地质出版社,1988:125-172.
[27]Donvan J J,Snyder D A,Rivers M L.An Improved Interference Correction for Trace Element Analysis[J].Microbeam Analysis,1993,2:23-28.
[28]Pyle J M,Spear F S,Wark D A.Electron Microprobe Analysis of REE in Apatite,Minazite and Xenotimeitfalls and Protocols[J].Reviews in Mineralogy and Geochemistry,2002,48:337-362.
[29]Pyle J M,Spear F S,Wark D A,et al.Contribution to Precision and Accuracy of Chemical Ages of Monazite[J].American Mineralogist,2005,90:547-577.
[30]Heluani S P.Invariant Embedding Approach for Electron Probe Microanalysis.Tilt Factor,Atomic Number and Energy of the Incident Electrons[J].X-ray Spectrom,2005,34 (3):230-23.
[31]Takahashi H,Harrowfield I,MacRae C,et al.Extended X-ray Emission Fine Structure and High Energy Satellite Lines State Measured by Electron Probe Microanalysis[J].Surface and Interface Analysis,2001,31:118-125.
[32]Jercinovic M J,Williams M L.Analytical Perils (and Progress) in Electron Microprobe Trace Element Analysis Applied to Geochronology:Background Acquisition,Interferences,and Beam Irradiation Effects[J].American Mineralogist,2005,90:526 -546.
[33]Reed S J B,Buckley A.Virtual WDS[J].Mikrochim Acta,1996,13 (suppl):479-483.
[34]Reed S J B,Buckley A.Rare-earth Element Deter -mination in Minerals by Electron-probe Microanalysis:Application of Spectrum Synthesis[J].Mineralogical Magazine,1998,62(1):1-8.
[35]Fournier C,Merlet C,Staub P F,et al.An Expert System for EPMA[J].Mikrochim Acta,2000,132:531-539.
[36]Newbury D E,Myklebust R L.Simulation of Electronexcited X-ray Spectra with NIST-NIH Desktop Spectrum Analyzer (DTSA)[J].Surface and Interface Analysis,2005,37 (11):1045-1053.
[37]张秀,刘辉,郑建斌,等.信号处理技术在重叠化学信号解析中的应用[J].化学进展,2002,14(3):174-181.
[38]Alexandrov P.Synneusis of Zircon:Why Not?[J].Mineralogical Magazine,2001,65 (1):71-79.
[39]Rémond G,Campbell J L,Packwood R H,et al.Spectral Decomposition of Wavelength Dispersive X-ray Spectra:Implications for Quantitative Analysis in the Electron Probe Microanalyzer[J].Scanning Microsc,1993,7(Suppl):89-132.
[40]陈光,任志良,孙海柱.最小二乘曲线拟合及Matlab实现[J].软件技术,2005,24(3):107-108.
[41]Dahl P S,Hamilton M A,Jercinovic M J,et al.Comparative Isotopic and Chemical Geochronometry of Monazite with Implications for U-Th-Pb Dating by Electron Microprobe:An Example from Metamorphic Rocks of the Eastern Wyoming Craton (U.S.A.)[J].American Mineralogist,2005,90:619-638.
[42]Fournier C,Merlet C,Duqne O,et al.Standardless Semi-quantitative Analysis with WDS-EPMA[J].Journal of Analytical Atomic Spectrometry,1999,14(3):381 -386.
[43]李德忍.矿物物理化学性质对电子探针定量分析精度的影响[J].分析仪器,1995,2:49-51.
[44]Trincavelli J,Castellano G,Riveros J A.Model for the Bremsstrahlung Spectrum in EPMA Application to Standardless Quantification[J].X-ray Spectrometry,1998,27:81-86.
[45]Reed S J B,Buckley A.Rare-earth Element Determination in Minerals by Electron-probe Microanalysis:Application of Spectrum Synthesis[J].Mineralogical Magazine,1998,62(1):1-8.
[46]Cocherie A,Albarede F.An Improved U-Th-Pb Age Calculation for Electron Microprobe Dating of Monazites[J].Geochim Cosmochim Acta,2001,65(24):4509-4522.
[47]Romanenko I M,Petroy D B.Potentials of Electron Probe Microanalysis in Studying Zircons[J].J Analytical Chemistry,2005,60 (10):942-945.
[48]Williams M L,Jercinovic M J,Terry M P.Age Mapping and Dating of Monazite on the Electron Microprobeeconvoluting Multi-stage Histories[J].Geology,1999,27:1023-1026.
[49]周剑雄,杨明明.微区痕量分析及其应用[J].国外矿床地质,1996a,2:77-107.
[50]Newbury D E.Quantitative Electron Probe Microanalysis of Rough Targets:Testing the Peak-to-Local Background Method[J].Scanning,2004,26(3):103-114.
[51]许德美,李峰,付晓旭.ITO靶材中含氧量EPMA定量分析方法研究[J].电子显微学报,2003,22(1):60-63.
[52]Kramers H A.On the Theory of X-ray Absorption and of.the Continuous X-ray Spectrum[J].Philosophical Magazine,1923,46:836-871.
[53]Lifshin E,Ciccarelli M F,Bolon R B.X-ray Spectral Measurement and Interpretation[M]//Practical Scanning Electron Microscopy.Goldstein J I,Yakowitz H,Eds.New York:Plenum Press,1975,Chap.7:263-297.
[54]Fiori C E,Myklebust R L,Heinrich K F J,et al.Prediction of Continuum Intensity in Energy-dispersive X-ray Microanalysis[J].Analytical Chemistry,1976,48:172-176.
[55]Reed S J B.Electron Microprobe Analysis[M].2nd Edition.Cambridge:Cambridge University Press,1993:326.
[56]Geisler T,Schleicher H.Improved U-Th-total Pb Dating of Zircons by Electron Microprobe Using a Simple New Background Modeling Procedure and Ca as a Chemical Criterion of Fluid-induced U-Th-Pb Discordance in Zircon[J].Chemical Geology,2000,163:269-285.
[57]Donovan J J,Tingle T N.An Improved Mean Atomic Number Correction for Quantitative Microanalysis[J].Journal of Microscopy,1996,21:1-7.
[58]Laputina I P,Batyrevb V A,Yakushev A I.A New EPMA Technique for Determination of Rare Earth Elements with the Use of Automated Peak-overlap and Modeled Background Corrections[J].Journal of Analysis Atomic Spectrometry,1999,14:465-469.
[59]Pouchou J L,Pichoir F.A New Model for Quantitative X-ray Microanalysis:Part Ⅰ.Application to the Analysis of Homogeneous Samples[J].Recherche Aerospatiale,1984,3:13-38.
[60]李德忍.电子探针分析微量元素的背景测定[J].分析测试通报,1987,6(3):46-48.
[61]张文兰,王汝成,蔡淑月.超轻元素Be元素的电子探针定量分析--以绿柱石为例[J].电子显微学报,2006,25(增刊):293-294.
[62]乔立山,王玉兰,曾锦光.实验数据处理中曲线拟合方法探讨[J].成都理工大学学报:自然科学版,2004,31(1):91-95.

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